Optical Outer-Sphere Charge Transfer in Ion Pairs with Peroxoborate as Donor
نویسنده
چکیده
Z. Naturforsch. 55 b, 1121-1123 (2000); received September 18, 2000 Charge Transfer, Peroxoborate, Chemiluminescence Peroxoborate and the oxidizing cations [Co(NH3)6]3+, [Ru(NH3)6]3+ and N,N'-dimethyl-4,4'bipyridinium2+ (paraquat2+) form ion pairs in aqueous solutions which display outer-sphere charge transfer (OSCT) bands in their absorption spectra. This CT involves an electronic transition from the peroxo substituents of peroxoborate to the cations. When 10,10'-dimethyl9,9'-biacridinium2+ (lucigenin2+, LG2+) is used as an electron acceptor an OSCT absorption is not observed owing to the instability of the ion pair LG2+ peroxoborate which undergoes a chemiluminescent conversion to N-methylacridone.
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